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Journal Article

Reductive Amination without an External Hydrogen Source

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Chusov,  Denis
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Chusov, D., & List, B. (2014). Reductive Amination without an External Hydrogen Source. Angewandte Chemie International Edition, 53(20), 5199-5201. doi:10.1002/anie.201400059.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-4BA3-E
Abstract
A method of reductive amination without an external hydrogen source is reported. Carbon monoxide is used as the reductant. The reaction proceeds efficiently for a variety of carbonyl compounds and amines at low catalyst loadings and is mechanistically interesting as it does not seem to involve molecular hydrogen.