Catalytic Asymmetric α-Amination of α-Branched Ketones via Enol Catalysis

Shevchenko, Grigory A.; Pupo, Gabriele; List, Benjamin

doi:10.1055/s-0034-1380680

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Catalytic Asymmetric α-Amination of α-Branched Ketones via Enol Catalysis

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Shevchenko, Grigory A.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Pupo, Gabriele
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Shevchenko, G. A., Pupo, G., & List, B. (2015). Catalytic Asymmetric α-Amination of α-Branched Ketones via Enol Catalysis. Synlett, 26(10), 1413-1416. doi:10.1055/s-0034-1380680.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0028-3010-7

Abstract

We report a highly enantioselective α-amination of α-branched ketones catalyzed by a chiral phosphoric acid employing azodicarboxylates as reagents. The desired products were obtained in good to excellent yields and enantioselectivities.