Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase 
Suzuki-Miyaura couplings

Steeples, Elliot; Kelling, Alexandra; Schilde, Uwe; Esposito, Davide

doi:10.1039/C5NJ03337C

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Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki-Miyaura couplings

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Steeples, Elliot
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Esposito, Davide
Davide Esposito, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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2262346.pdf
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2262346_supp.pdf
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引用

Steeples, E., Kelling, A., Schilde, U., & Esposito, D. (2016). Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki-Miyaura couplings. New Journal of Chemistry, 40(6), 4922-4930. doi:10.1039/C5NJ03337C.

引用: https://hdl.handle.net/11858/00-001M-0000-002A-2345-D

要旨

In this work, three ligands produced from amino acids were synthesized and used to produce five bis- and PEPPSI-type palladium-NHC complexes using a novel synthesis route from sustainable starting materials. Three of these complexes were used as precatalysts in the aqueous-phase Suzuki-Miyaura coupling of various substrates displaying high activity. TEM and mercury poisoning experiments provide evidence for Pd-nanoparticle formation stabilized in water.