date: 2012-09-28T08:54:45Z
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pdf:docinfo:title: {4,4'-Dimethoxy-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
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dc:description: The asymmetric unit of the title compound, [Cu(C21H24N2O4)].H2O, comprises half of a Schiff base complex and a water molecule. The CuII atom, water molecule and one C atom of the central propylene segment are located on a twofold rotation axis. The geometry around the CuII atom is distorted square-planar, supported by the N2O2 donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)degrees. In the crystal, O-H...O hydrogen bonds involving the water molecule make an R21(6) ring motif. Complex molecules are linked into a chain along the c axis via C-H...O interactions.
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description: The asymmetric unit of the title compound, [Cu(C21H24N2O4)].H2O, comprises half of a Schiff base complex and a water molecule. The CuII atom, water molecule and one C atom of the central propylene segment are located on a twofold rotation axis. The geometry around the CuII atom is distorted square-planar, supported by the N2O2 donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)degrees. In the crystal, O-H...O hydrogen bonds involving the water molecule make an R21(6) ring motif. Complex molecules are linked into a chain along the c axis via C-H...O interactions.
dcterms:created: 2012-09-12T12:00:00Z
Last-Modified: 2012-09-28T08:54:45Z
dcterms:modified: 2012-09-28T08:54:45Z
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title: {4,4'-Dimethoxy-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
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dc:title: {4,4'-Dimethoxy-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
modified: 2012-09-28T08:54:45Z
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Creation-Date: 2012-09-12T12:00:00Z
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producer: International Union of Crystallography
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pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2012-09-12T12:00:00Z