date: 2012-08-30T09:00:22Z
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pdf:docinfo:title: {4,4'-Dimethyl-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
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dc:description: The asymmetric unit of the title compound, [Cu(C21H24N2O2)].H2O, comprises half of a Schiff base complex and half of a water molecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)degrees. In the crystal, the water molecule that is hydrogen bonded to the coordinated O atoms links the molecules via O-H...O interactions into chains parallel to [001]. The crystal structure is further stabilized by C-H...[pi] interactions, and by [pi]-[pi] interactions involving inversion-related chelate rings [centroid-centroid distance = 3.480 (4) A].
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description: The asymmetric unit of the title compound, [Cu(C21H24N2O2)].H2O, comprises half of a Schiff base complex and half of a water molecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)degrees. In the crystal, the water molecule that is hydrogen bonded to the coordinated O atoms links the molecules via O-H...O interactions into chains parallel to [001]. The crystal structure is further stabilized by C-H...[pi] interactions, and by [pi]-[pi] interactions involving inversion-related chelate rings [centroid-centroid distance = 3.480 (4) A].
dcterms:created: 2012-08-11T12:00:00Z
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dcterms:modified: 2012-08-30T09:00:22Z
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title: {4,4'-Dimethyl-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
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dc:title: {4,4'-Dimethyl-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
modified: 2012-08-30T09:00:22Z
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producer: International Union of Crystallography
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pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2012-08-11T12:00:00Z