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pdf:docinfo:title: {5,5'-Bis(diethylamino)-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)
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dc:description: In the title compound, [Mo(C27H38N4O2)O2], the MoVI atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate Schiff base ligand in a distorted octahedral geometry. The Mo-N bond trans to a terminal oxide group is significantly longer than the other Mo-N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)degrees. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).
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description: In the title compound, [Mo(C27H38N4O2)O2], the MoVI atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate Schiff base ligand in a distorted octahedral geometry. The Mo-N bond trans to a terminal oxide group is significantly longer than the other Mo-N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)degrees. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).
dcterms:created: 2011-09-14T12:00:00Z
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dcterms:modified: 2015-05-15T10:42:08Z
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title: {5,5'-Bis(diethylamino)-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)
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dc:title: {5,5'-Bis(diethylamino)-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI)
modified: 2015-05-15T10:42:08Z
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meta:creation-date: 2011-09-14T12:00:00Z
created: 2011-09-14T12:00:00Z
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Creation-Date: 2011-09-14T12:00:00Z
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producer: International Union of Crystallography
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pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2011-09-14T12:00:00Z