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pdf:docinfo:title: {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II)
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dc:description: The asymmetric unit of the title compound, [Ni(C19H16I4N2O2)], comprises half of a Schiff base complex. The NiII atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the NiII atom is distorted square-planar, with a dihedral angle of 21.7 (3)degrees between the symmetry-related N/Ni/O coordination planes. The dihedral angle between the symmetry-related benzene rings is 27.9 (3)degrees. In the crystal, short intermolecular I...I [3.8178 (9) and 3.9013 (10) A] interactions are present.
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description: The asymmetric unit of the title compound, [Ni(C19H16I4N2O2)], comprises half of a Schiff base complex. The NiII atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the NiII atom is distorted square-planar, with a dihedral angle of 21.7 (3)degrees between the symmetry-related N/Ni/O coordination planes. The dihedral angle between the symmetry-related benzene rings is 27.9 (3)degrees. In the crystal, short intermolecular I...I [3.8178 (9) and 3.9013 (10) A] interactions are present.
dcterms:created: 2012-06-16T12:00:00Z
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dcterms:modified: 2015-05-17T10:45:49Z
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title: {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II)
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dc:title: {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II)
modified: 2015-05-17T10:45:49Z
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meta:creation-date: 2012-06-16T12:00:00Z
created: 2012-06-16T12:00:00Z
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Creation-Date: 2012-06-16T12:00:00Z
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producer: International Union of Crystallography
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pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2012-06-16T12:00:00Z