##############################################################################
### ###
### Electronic paper (Acta Crystallographica Section E) ###
### ###
##############################################################################
# #
# This CIF contains the data in a paper accepted for publication in Acta #
# Crystallographica Section E. It conforms to the requirements of Notes #
# for Authors for Section E, and has been peer reviewed under the auspices #
# of the IUCr Commission on Journals. #
# #
# Full details of the Crystallographic Information File format #
# are given in the paper "The Crystallographic Information File (CIF): #
# a New Standard Archive File for Crystallography" by S. R. Hall, F. H. #
# Allen and I. D. Brown [Acta Cryst. (1991), A47, 655-685]. #
# #
# The current version of the core CIF dictionary is obtainable from #
# ftp://ftp.iucr.org/pub/cif_core.dic. The current version number is 2.4. #
# #
# Software is freely available for graphical display of the structure(s) in #
# this CIF. For information consult the CIF home page http://www.iucr.org/ #
# cif/home.html #
# #
# This file may be used for bona fide research purposes within the #
# scientific community so long as proper attribution is given to the journal #
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data_global
_audit_creation_method 'form.cif (version 2.0)'
_journal_data_validation_number ?
_journal_date_recd_electronic 2011-01-02
_journal_date_accepted 2011-01-07
_journal_name_full 'Acta Crystallographica, Section E'
_journal_year 2011
_journal_volume 67
_journal_issue 2
_journal_page_first o367
_journal_page_last o367
_journal_paper_category QO
_journal_coeditor_code JH2253
loop_
_publ_contact_author_name
_publ_contact_author_address
_publ_contact_author_email
'Prof. Tahir, Muhammad Nawaz'
;
Department of Physics
University of Sargodha
Punjab, Pakistan
;
'dmntahir_uos@yahoo.com'
'Kia, Reza'
;
X-ray Crystallography Lab.,
Plasma Physics Research Center,
Science and Research Branch,
Islamic Azad University,
Tehran,
Iran and
Department of Chemistry,
Science and Research Branch,
Islamic Azad University,
Tehran,
Iran
;
'rkia@srbiau.ac.ir, zsrkk@yahoo.com'
_publ_contact_author_fax ?
_publ_contact_author_phone ?
_publ_section_title
;\
(Furan-2-yl)(5-hydroxy-3-methyl-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl)\
methanone
;
loop_
_publ_author_name
_publ_author_address
'Kargar, Hadi'
;
Department of Chemistry,
School of Science,
Payame Noor University (PNU),
Ardakan, Yazd,
Iran
;
'Kia, Reza'
;
X-ray Crystallography Lab.,
Plasma Physics Research Center,
Science and Research Branch,
Islamic Azad University,
Tehran,
Iran and
Department of Chemistry,
Science and Research Branch,
Islamic Azad University,
Tehran,
Iran
;
'Moghadamm, Majid'
;
Department of Chemistry,
Catalysis Division,
University of Isfahan,
Isfahan 81746-73441,
Iran
;
'Tahir, Muhammad Nawaz'
;
Department of Physics
University of Sargodha
Punjab, Pakistan
;
data_I
_audit_creation_method SHELXL-97
_chemical_name_systematic
;
(Furan-2-yl)(5-hydroxy-3-methyl-5-phenyl-4,5-dihydro-1H-
pyrazol-1-yl)methanone
;
_chemical_name_common
;
;
_chemical_formula_moiety 'C15 H14 N2 O3'
_chemical_formula_sum 'C15 H14 N2 O3'
_chemical_formula_iupac 'C15 H14 N2 O3'
_chemical_formula_weight 270.28
_chemical_melting_point ?
_symmetry_cell_setting monoclinic
_symmetry_space_group_name_H-M 'P 21/n'
_symmetry_space_group_name_Hall '-P 2yn'
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
_cell_length_a 10.6844(10)
_cell_length_b 8.4700(7)
_cell_length_c 15.3022(16)
_cell_angle_alpha 90.00
_cell_angle_beta 95.266(3)
_cell_angle_gamma 90.00
_cell_volume 1379.0(2)
_cell_formula_units_Z 4
_cell_measurement_reflns_used 2245
_cell_measurement_theta_min 2.45
_cell_measurement_theta_max 29.45
_cell_measurement_temperature 296(2)
_exptl_crystal_description 'block'
_exptl_crystal_colour 'white'
_exptl_crystal_size_max 0.28
_exptl_crystal_size_mid 0.22
_exptl_crystal_size_min 0.16
_exptl_crystal_density_diffrn 1.302
_exptl_crystal_density_meas ?
_exptl_crystal_density_method 'not measured'
_exptl_crystal_F_000 568
_exptl_absorpt_coefficient_mu 0.092
_exptl_absorpt_correction_type multi-scan
_exptl_absorpt_process_details '(SADABS; Bruker, 2005)'
_exptl_absorpt_correction_T_min 0.9746
_exptl_absorpt_correction_T_max 0.9854
_exptl_special_details ?
_diffrn_ambient_temperature 296(2)
_diffrn_radiation_type MoK\a
_diffrn_radiation_wavelength 0.71073
_diffrn_radiation_source 'fine-focus sealed tube'
_diffrn_radiation_monochromator graphite
_diffrn_measurement_device_type
;
Bruker SMART APEXII CCD area-detector
;
_diffrn_measurement_method '\f and \w'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number 10534
_diffrn_reflns_av_R_equivalents 0.0444
_diffrn_reflns_av_sigmaI/netI 0.0418
_diffrn_reflns_theta_min 2.43
_diffrn_reflns_theta_max 25.24
_diffrn_reflns_theta_full 25.24
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_limit_h_min -12
_diffrn_reflns_limit_h_max 12
_diffrn_reflns_limit_k_min -10
_diffrn_reflns_limit_k_max 10
_diffrn_reflns_limit_l_min -18
_diffrn_reflns_limit_l_max 18
_diffrn_standards_number 0
_diffrn_standards_interval_count .
_diffrn_standards_interval_time .
_diffrn_standards_decay_% ?
_refine_special_details
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_reflns_number_total 2495
_reflns_number_gt 1615
_reflns_threshold_expression I>2\s(I)
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type full
_refine_ls_R_factor_all 0.0743
_refine_ls_R_factor_gt 0.0417
_refine_ls_wR_factor_gt 0.0911
_refine_ls_wR_factor_ref 0.1058
_refine_ls_goodness_of_fit_ref 1.030
_refine_ls_restrained_S_all 1.028
_refine_ls_number_reflns 2495
_refine_ls_number_parameters 221
_refine_ls_number_restraints 10
_refine_ls_hydrogen_treatment constr
_refine_ls_weighting_scheme calc
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0370P)^2^+0.1913P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_hydrogens geom
_atom_sites_solution_primary direct
_atom_sites_solution_secondary difmap
_refine_ls_shift/su_max 0.000
_refine_ls_shift/su_mean 0.000
_refine_diff_density_max 0.123
_refine_diff_density_min -0.127
_refine_ls_extinction_method 'SHELXTL (Sheldrick, 2008)'
_refine_ls_extinction_coef 0.0132(14)
_refine_ls_extinction_expression
'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
'C' 'C' 0.0033 0.0016
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
'H' 'H' 0.0000 0.0000
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
'N' 'N' 0.0061 0.0033
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
'O' 'O' 0.0106 0.0060
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_computing_data_collection 'APEX2 (Bruker, 2005)'
_computing_cell_refinement 'SAINT (Bruker, 2005)'
_computing_data_reduction 'SAINT (Bruker, 2005)'
_computing_structure_solution 'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement 'SHELXTL (Sheldrick, 2008)'
_computing_molecular_graphics 'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
;
SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009)
;
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O O1 0.39871(12) 1.05521(16) 0.13086(9) 0.0564(4) Uani d . 1 . .
H H1 0.4501 1.0373 0.0954 0.085 Uiso calc R 1 . .
O O2 0.37249(12) 0.97468(15) -0.05954(9) 0.0540(4) Uani d . 1 . .
N N1 0.11933(14) 1.14352(17) 0.03952(12) 0.0530(5) Uani d . 1 . .
N N2 0.22305(14) 1.04995(17) 0.02389(10) 0.0463(4) Uani d . 1 . .
C C1 0.30125(18) 0.8002(2) 0.09202(12) 0.0467(5) Uani d . 1 . .
C C2 0.4147(2) 0.7260(2) 0.10936(14) 0.0605(6) Uani d . 1 . .
H H2 0.4856 0.7842 0.1289 0.073 Uiso calc R 1 . .
C C3 0.4242(3) 0.5637(3) 0.09779(18) 0.0803(8) Uani d . 1 . .
H H3 0.5016 0.5142 0.1091 0.096 Uiso calc R 1 . .
C C4 0.3208(3) 0.4768(3) 0.0700(2) 0.0916(9) Uani d . 1 . .
H H4 0.3272 0.3682 0.0630 0.110 Uiso calc R 1 . .
C C5 0.2085(3) 0.5500(3) 0.0528(2) 0.0909(9) Uani d . 1 . .
H H5 0.1378 0.4910 0.0337 0.109 Uiso calc R 1 . .
C C6 0.1979(2) 0.7105(2) 0.06307(16) 0.0704(7) Uani d . 1 . .
H H6 0.1203 0.7591 0.0504 0.085 Uiso calc R 1 . .
C C7 0.28639(17) 0.9765(2) 0.10487(13) 0.0455(5) Uani d . 1 . .
C C8 0.19276(18) 1.0218(2) 0.17109(14) 0.0569(6) Uani d . 1 . .
H H8A 0.1500 0.9292 0.1909 0.068 Uiso calc R 1 . .
H H8B 0.2350 1.0751 0.2216 0.068 Uiso calc R 1 . .
C C9 0.10301(18) 1.1294(2) 0.12079(15) 0.0545(5) Uani d . 1 . .
C C10 0.0004(2) 1.2167(3) 0.15998(16) 0.0818(8) Uani d . 1 . .
H H10A -0.0483 1.1441 0.1912 0.123 Uiso calc R 1 . .
H H10B -0.0530 1.2667 0.1142 0.123 Uiso calc R 1 . .
H H10C 0.0363 1.2955 0.1998 0.123 Uiso calc R 1 . .
C C11 0.27454(17) 1.0491(2) -0.05355(13) 0.0436(5) Uani d . 1 A .
C C12 0.21378(16) 1.1311(2) -0.12971(12) 0.0497(5) Uani d D 1 . .
C C13 0.1182(12) 1.2333(18) -0.1440(6) 0.071(3) Uani d PD 0.587(11) A 1
H H13A 0.0724 1.2811 -0.1024 0.085 Uiso calc PR 0.587(11) A 1
C C14 0.1026(12) 1.2525(13) -0.2367(6) 0.071(3) Uani d PD 0.587(11) A 1
H H14A 0.0360 1.3042 -0.2680 0.086 Uiso calc PR 0.587(11) A 1
C C15 0.1996(12) 1.1838(19) -0.2715(7) 0.076(3) Uani d PD 0.587(11) A 1
H H15A 0.2191 1.1926 -0.3293 0.092 Uiso calc PR 0.587(11) A 1
O O3 0.2646(7) 1.0983(13) -0.2065(3) 0.072(2) Uani d PD 0.587(11) A 1
C C13X 0.2557(15) 1.136(2) -0.2096(5) 0.060(4) Uani d PD 0.413(11) A 2
H H13B 0.3305 1.0955 -0.2267 0.072 Uiso calc PR 0.413(11) A 2
C C14X 0.1599(14) 1.2180(19) -0.2623(9) 0.058(3) Uani d PD 0.413(11) A 2
H H14B 0.1533 1.2220 -0.3233 0.070 Uiso calc PR 0.413(11) A 2
C C15X 0.0807(19) 1.2883(19) -0.2115(8) 0.079(4) Uani d PD 0.413(11) A 2
H H15B 0.0241 1.3695 -0.2263 0.095 Uiso calc PR 0.413(11) A 2
O O3X 0.1028(10) 1.212(2) -0.1327(7) 0.078(4) Uani d PD 0.413(11) A 2
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
O1 0.0494(8) 0.0629(8) 0.0569(10) -0.0070(7) 0.0048(7) -0.0151(7)
O2 0.0469(8) 0.0640(9) 0.0518(9) 0.0075(7) 0.0087(7) 0.0015(7)
N1 0.0495(10) 0.0503(9) 0.0598(12) 0.0080(8) 0.0091(9) -0.0036(8)
N2 0.0456(9) 0.0460(9) 0.0478(10) 0.0066(7) 0.0073(8) 0.0019(7)
C1 0.0492(12) 0.0482(11) 0.0430(12) 0.0013(9) 0.0049(9) 0.0042(9)
C2 0.0586(14) 0.0577(13) 0.0655(15) 0.0065(11) 0.0072(11) 0.0096(11)
C3 0.0848(18) 0.0643(15) 0.094(2) 0.0285(14) 0.0197(15) 0.0189(14)
C4 0.117(2) 0.0473(14) 0.112(2) 0.0000(16) 0.020(2) 0.0009(14)
C5 0.095(2) 0.0573(15) 0.118(3) -0.0145(14) -0.0025(18) -0.0073(15)
C6 0.0640(15) 0.0533(13) 0.0916(19) -0.0053(11) -0.0059(13) -0.0008(12)
C7 0.0431(11) 0.0502(11) 0.0433(12) -0.0004(9) 0.0034(9) -0.0034(9)
C8 0.0566(13) 0.0637(13) 0.0514(13) 0.0015(10) 0.0109(10) -0.0045(10)
C9 0.0485(12) 0.0564(12) 0.0592(15) 0.0021(10) 0.0083(11) -0.0080(11)
C10 0.0691(16) 0.1043(19) 0.0746(18) 0.0238(14) 0.0214(13) -0.0108(14)
C11 0.0408(11) 0.0404(10) 0.0495(13) -0.0054(9) 0.0034(9) -0.0008(9)
C12 0.0458(12) 0.0492(12) 0.0540(14) -0.0057(10) 0.0041(10) 0.0066(10)
C13 0.063(5) 0.076(5) 0.075(7) 0.026(4) 0.016(4) 0.030(5)
C14 0.070(7) 0.082(6) 0.060(6) 0.034(5) -0.006(5) 0.013(6)
C15 0.062(7) 0.118(10) 0.050(4) -0.013(4) 0.009(4) 0.022(5)
O3 0.075(3) 0.082(6) 0.057(3) -0.007(2) -0.001(2) 0.0081(18)
C13X 0.075(7) 0.050(6) 0.061(8) 0.000(4) 0.032(7) 0.006(4)
C14X 0.062(12) 0.065(8) 0.051(6) 0.005(7) 0.016(5) 0.011(5)
C15X 0.106(9) 0.073(7) 0.059(7) 0.033(5) 0.009(6) 0.010(6)
O3X 0.066(5) 0.100(7) 0.067(5) 0.015(4) 0.003(4) 0.038(4)
_geom_special_details
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
O1 C7 . 1.398(2) ?
O1 H1 . 0.8200 ?
O2 C11 . 1.232(2) ?
N1 C9 . 1.277(2) ?
N1 N2 . 1.401(2) ?
N2 C11 . 1.352(2) ?
N2 C7 . 1.492(2) ?
C1 C2 . 1.370(3) ?
C1 C6 . 1.380(3) ?
C1 C7 . 1.516(3) ?
C2 C3 . 1.390(3) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.363(3) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.355(4) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.374(3) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
C7 C8 . 1.536(3) ?
C8 C9 . 1.486(3) ?
C8 H8A . 0.9700 ?
C8 H8B . 0.9700 ?
C9 C10 . 1.493(3) ?
C10 H10A . 0.9600 ?
C10 H10B . 0.9600 ?
C10 H10C . 0.9600 ?
C11 C12 . 1.457(2) ?
C12 C13X . 1.3407(11) ?
C12 C13 . 1.3407(10) ?
C12 O3 . 1.3670(10) ?
C12 O3X . 1.3677(10) ?
C13 C14 . 1.4230(11) ?
C13 H13A . 0.9300 ?
C14 C15 . 1.3407(10) ?
C14 H14A . 0.9300 ?
C15 O3 . 1.3679(10) ?
C15 H15A . 0.9300 ?
C13X C14X . 1.4230(10) ?
C13X H13B . 0.9300 ?
C14X C15X . 1.3406(10) ?
C14X H14B . 0.9300 ?
C15X O3X . 1.3679(10) ?
C15X H15B . 0.9300 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C7 O1 H1 . . 109.5 ?
C9 N1 N2 . . 107.11(16) ?
C11 N2 N1 . . 123.00(16) ?
C11 N2 C7 . . 122.41(15) ?
N1 N2 C7 . . 113.55(15) ?
C2 C1 C6 . . 118.50(19) ?
C2 C1 C7 . . 121.90(18) ?
C6 C1 C7 . . 119.60(17) ?
C1 C2 C3 . . 120.2(2) ?
C1 C2 H2 . . 119.9 ?
C3 C2 H2 . . 119.9 ?
C4 C3 C2 . . 120.5(2) ?
C4 C3 H3 . . 119.8 ?
C2 C3 H3 . . 119.8 ?
C5 C4 C3 . . 119.5(2) ?
C5 C4 H4 . . 120.3 ?
C3 C4 H4 . . 120.3 ?
C4 C5 C6 . . 120.7(2) ?
C4 C5 H5 . . 119.6 ?
C6 C5 H5 . . 119.6 ?
C5 C6 C1 . . 120.7(2) ?
C5 C6 H6 . . 119.7 ?
C1 C6 H6 . . 119.7 ?
O1 C7 N2 . . 110.47(15) ?
O1 C7 C1 . . 114.13(15) ?
N2 C7 C1 . . 110.34(15) ?
O1 C7 C8 . . 106.70(15) ?
N2 C7 C8 . . 99.82(14) ?
C1 C7 C8 . . 114.43(16) ?
C9 C8 C7 . . 103.87(17) ?
C9 C8 H8A . . 111.0 ?
C7 C8 H8A . . 111.0 ?
C9 C8 H8B . . 111.0 ?
C7 C8 H8B . . 111.0 ?
H8A C8 H8B . . 109.0 ?
N1 C9 C8 . . 114.99(17) ?
N1 C9 C10 . . 121.0(2) ?
C8 C9 C10 . . 124.0(2) ?
C9 C10 H10A . . 109.5 ?
C9 C10 H10B . . 109.5 ?
H10A C10 H10B . . 109.5 ?
C9 C10 H10C . . 109.5 ?
H10A C10 H10C . . 109.5 ?
H10B C10 H10C . . 109.5 ?
O2 C11 N2 . . 118.98(17) ?
O2 C11 C12 . . 120.23(17) ?
N2 C11 C12 . . 120.77(16) ?
C13X C12 C13 . . 98.3(7) ?
C13 C12 O3 . . 110.4(5) ?
C13X C12 O3X . . 108.3(7) ?
O3 C12 O3X . . 119.0(6) ?
C13X C12 C11 . . 125.7(6) ?
C13 C12 C11 . . 135.6(4) ?
O3 C12 C11 . . 114.0(4) ?
O3X C12 C11 . . 126.0(5) ?
C12 C13 C14 . . 104.7(6) ?
C12 C13 H13A . . 127.7 ?
C14 C13 H13A . . 127.7 ?
C15 C14 C13 . . 108.8(9) ?
C15 C14 H14A . . 125.6 ?
C13 C14 H14A . . 125.6 ?
C14 C15 O3 . . 107.5(8) ?
C14 C15 H15A . . 126.3 ?
O3 C15 H15A . . 126.3 ?
C12 O3 C15 . . 107.6(7) ?
C12 C13X C14X . . 104.4(8) ?
C12 C13X H13B . . 127.8 ?
C14X C13X H13B . . 127.8 ?
C15X C14X C13X . . 110.3(13) ?
C15X C14X H14B . . 124.8 ?
C13X C14X H14B . . 124.8 ?
C14X C15X O3X . . 103.6(11) ?
C14X C15X H15B . . 128.2 ?
O3X C15X H15B . . 128.2 ?
C12 O3X C15X . . 110.2(10) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C9 N1 N2 C11 . . . . -173.27(17) ?
C9 N1 N2 C7 . . . . -4.7(2) ?
C6 C1 C2 C3 . . . . 0.0(3) ?
C7 C1 C2 C3 . . . . 179.19(19) ?
C1 C2 C3 C4 . . . . -0.7(4) ?
C2 C3 C4 C5 . . . . 0.7(4) ?
C3 C4 C5 C6 . . . . -0.1(4) ?
C4 C5 C6 C1 . . . . -0.6(4) ?
C2 C1 C6 C5 . . . . 0.6(3) ?
C7 C1 C6 C5 . . . . -178.6(2) ?
C11 N2 C7 O1 . . . . 64.3(2) ?
N1 N2 C7 O1 . . . . -104.43(16) ?
C11 N2 C7 C1 . . . . -62.9(2) ?
N1 N2 C7 C1 . . . . 128.44(15) ?
C11 N2 C7 C8 . . . . 176.34(16) ?
N1 N2 C7 C8 . . . . 7.66(18) ?
C2 C1 C7 O1 . . . . 3.3(3) ?
C6 C1 C7 O1 . . . . -177.48(18) ?
C2 C1 C7 N2 . . . . 128.39(19) ?
C6 C1 C7 N2 . . . . -52.4(2) ?
C2 C1 C7 C8 . . . . -120.0(2) ?
C6 C1 C7 C8 . . . . 59.2(2) ?
O1 C7 C8 C9 . . . . 107.68(17) ?
N2 C7 C8 C9 . . . . -7.31(18) ?
C1 C7 C8 C9 . . . . -125.09(17) ?
N2 N1 C9 C8 . . . . -0.9(2) ?
N2 N1 C9 C10 . . . . 179.00(18) ?
C7 C8 C9 N1 . . . . 5.7(2) ?
C7 C8 C9 C10 . . . . -174.22(19) ?
N1 N2 C11 O2 . . . . 173.43(16) ?
C7 N2 C11 O2 . . . . 5.8(2) ?
N1 N2 C11 C12 . . . . -8.3(3) ?
C7 N2 C11 C12 . . . . -175.89(16) ?
O2 C11 C12 C13X . . . . -0.8(13) ?
N2 C11 C12 C13X . . . . -179.1(12) ?
O2 C11 C12 C13 . . . . -171.2(12) ?
N2 C11 C12 C13 . . . . 10.5(13) ?
O2 C11 C12 O3 . . . . 8.7(6) ?
N2 C11 C12 O3 . . . . -169.6(5) ?
O2 C11 C12 O3X . . . . 177.3(10) ?
N2 C11 C12 O3X . . . . -1.0(11) ?
C13X C12 C13 C14 . . . . 13.4(15) ?
O3 C12 C13 C14 . . . . 5.6(16) ?
O3X C12 C13 C14 . . . . -128(6) ?
C11 C12 C13 C14 . . . . -174.5(6) ?
C12 C13 C14 C15 . . . . -9.9(18) ?
C13 C14 C15 O3 . . . . 10.3(19) ?
C13X C12 O3 C15 . . . . -33(5) ?
C13 C12 O3 C15 . . . . 0.5(15) ?
O3X C12 O3 C15 . . . . 11.1(13) ?
C11 C12 O3 C15 . . . . -179.5(9) ?
C14 C15 O3 C12 . . . . -6.8(17) ?
C13 C12 C13X C14X . . . . -11.5(17) ?
O3 C12 C13X C14X . . . . 137(6) ?
O3X C12 C13X C14X . . . . -3(2) ?
C11 C12 C13X C14X . . . . 175.3(9) ?
C12 C13X C14X C15X . . . . 14(2) ?
C13X C14X C15X O3X . . . . -18(2) ?
C13X C12 O3X C15X . . . . -8(2) ?
C13 C12 O3X C15X . . . . 32(5) ?
O3 C12 O3X C15X . . . . -18.4(19) ?
C11 C12 O3X C15X . . . . 173.5(11) ?
C14X C15X O3X C12 . . . . 16(2) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O1 H1 O2 3_675 0.82 2.02 2.7786(18) 153 y
C14 H14A O1 4_585 0.93 2.36 3.271(9) 168 y