date: 2018-02-28T09:20:29Z
pdf:unmappedUnicodeCharsPerPage: 2
pdf:PDFVersion: 1.3
pdf:docinfo:title: X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell
xmp:CreatorTool: pdftk 1.44 - www.pdftk.com
dc:description: The effects of varying LiPF6 salt concentration and the presence of lithium bis(oxalate)borate additive on the electronic structure of commonly used lithium-ion battery electrolyte solvents (ethylene carbonate-dimethyl carbonate and propylene carbonate) have been investigated. X-ray Raman scattering spectroscopy (a non-resonant inelastic X-ray scattering method) was utilized together with a closed-circle flow cell. Carbon and oxygen K-edges provide characteristic information on the electronic structure of the electrolyte solutions, which are sensitive to local chemistry. Higher Li+ ion concentration in the solvent manifests itself as a blue-shift of both the [pi]* feature in the carbon edge and the carbonyl [pi]* feature in the oxygen edge. While these oxygen K-edge results agree with previous soft X-ray absorption studies on LiBF4 salt concentration in propylene carbonate, carbon K-edge spectra reveal a shift in energy, which can be explained with differing ionic conductivities of the electrolyte solutions.
access_permission:modify_annotations: true
access_permission:can_print_degraded: true
description: The effects of varying LiPF6 salt concentration and the presence of lithium bis(oxalate)borate additive on the electronic structure of commonly used lithium-ion battery electrolyte solvents (ethylene carbonate-dimethyl carbonate and propylene carbonate) have been investigated. X-ray Raman scattering spectroscopy (a non-resonant inelastic X-ray scattering method) was utilized together with a closed-circle flow cell. Carbon and oxygen K-edges provide characteristic information on the electronic structure of the electrolyte solutions, which are sensitive to local chemistry. Higher Li+ ion concentration in the solvent manifests itself as a blue-shift of both the [pi]* feature in the carbon edge and the carbonyl [pi]* feature in the oxygen edge. While these oxygen K-edge results agree with previous soft X-ray absorption studies on LiBF4 salt concentration in propylene carbonate, carbon K-edge spectra reveal a shift in energy, which can be explained with differing ionic conductivities of the electrolyte solutions.
dcterms:created: 2018-02-21T12:00:00Z
Last-Modified: 2018-02-28T09:20:29Z
dcterms:modified: 2018-02-28T09:20:29Z
dc:format: application/pdf; version=1.3
title: X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell
Last-Save-Date: 2018-02-28T09:20:29Z
pdf:docinfo:creator_tool: pdftk 1.44 - www.pdftk.com
access_permission:fill_in_form: true
pdf:docinfo:modified: 2018-02-28T09:20:29Z
meta:save-date: 2018-02-28T09:20:29Z
pdf:encrypted: false
dc:title: X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell
modified: 2018-02-28T09:20:29Z
Content-Type: application/pdf
X-Parsed-By: org.apache.tika.parser.DefaultParser
meta:creation-date: 2018-02-21T12:00:00Z
created: 2018-02-21T12:00:00Z
access_permission:extract_for_accessibility: true
access_permission:assemble_document: true
xmpTPg:NPages: 6
Creation-Date: 2018-02-21T12:00:00Z
pdf:charsPerPage: 3455
access_permission:extract_content: true
access_permission:can_print: true
producer: International Union of Crystallography
access_permission:can_modify: true
pdf:docinfo:producer: International Union of Crystallography
pdf:docinfo:created: 2018-02-21T12:00:00Z