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Tobias Keßler
Christian Kunde
Steffen Linke
Kevin McBride
Kai Sundmacher and Achim Kienle
green solvents
hydroformylation
TMS
BARON
process optimization
Including ecologic and environmental aspects in chemical engineering requires new methods for process design and optimization. In this work, a hydroformylation process of long-chain olefines is investigated. A thermomorphic multiphase system is employed that is homogeneous at reaction conditions and biphasic at lower temperatures for catalyst recycling. In an attempt to replace the toxic polar solvent N,N-dimethylformamide (DMF), ecologically benign alternatives are selected using a screening approach. Economic process optimization is conducted for DMF and two candidate solvents. It is found that one of the green candidates performs similarly well as the standard benchmark solvent DMF, without being toxic. Therefore, the candidate has the potential to replace it.
Systematic Selection of Green Solvents and Process Optimization for the Hydroformylation of Long-Chain Olefines
application/pdf
2019-11-26T14:31:14+01:00
LaTeX with hyperref package
2019-12-04T14:21:18+01:00
green solvents; hydroformylation; TMS; BARON; process optimization
pdfTeX-1.40.17
This is pdfTeX, Version 3.14159265-2.6-1.40.17 (TeX Live 2016/W32TeX) kpathsea version 6.2.2
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