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Correction to "Dinitrogen Fixation and Reduction by Ta3N3H0,1- Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity"

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Yubero Valdivielso,  David
Institute for Optics and Atomic Physics, Technische Universität Berlin;
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Fielicke,  André
Institute for Optics and Atomic Physics, Technische Universität Berlin;
Molecular Physics, Fritz Haber Institute, Max Planck Society;

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Citation

Zhao, Y., Cui, J.-T., Wang, M., Yubero Valdivielso, D., Fielicke, A., Hu, L.-R., et al. (2019). Correction to "Dinitrogen Fixation and Reduction by Ta3N3H0,1- Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity". Journal of the American Chemical Society, 141(36), 14460-14460. doi:10.1021/jacs.9b08813.


Cite as: https://hdl.handle.net/21.11116/0000-0006-C085-A
Abstract
Page 12593, lines 6–7. In the beginning of the fourth sentence in the second paragraph of the Introduction, the text, “In addition to Os,42 Sc2,36 Ti2,35 Ta2+,56 and Ta2C4- ,55 ,” should be replaced by “Except for Os...”.

In fact, all the Os, Sc2, Ti2, Ta2+, and Ta2C4- species are proven to be capable of N2 activation and cannot be included (as the sentence goes on to state) among “most of the transition metal atoms and clusters M” which “adsorb one or several N2 molecules with the formation of physisorbed M(NN)n complexes”.