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Nonlinear dispersion in resonant Auger decay of H2O molecules

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Piancastelli,  Maria Novella
Fritz Haber Institute, Max Planck Society;
Department of Chemical Sciences and Technologies, Università “Tor Vergata,”, Italy;

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Kempgens,  Brigitte
Fritz Haber Institute, Max Planck Society;

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Hergenhahn,  Uwe
Fritz Haber Institute, Max Planck Society;

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Maier,  Klaus
Fritz Haber Institute, Max Planck Society;

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Rüdel,  Andy
Fritz Haber Institute, Max Planck Society;

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Bradshaw,  Alexander M.
Fritz Haber Institute, Max Planck Society;

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PhysRevA.59.1336.pdf
(Publisher version), 94KB

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Citation

Piancastelli, M. N., Kempgens, B., Hergenhahn, U., Kivimäki, A., Maier, K., Rüdel, A., et al. (1999). Nonlinear dispersion in resonant Auger decay of H2O molecules. Physical Review A, 59(2), 1336-1340. doi:10.1103/PhysRevA.59.1336.


Cite as: https://hdl.handle.net/21.11116/0000-0008-C905-0
Abstract
We have measured the resonant Auger decay spectrum of the water molecule at the oxygen K edge. Strong deviations from the expected linear dispersion of the participator lines (which correspond to single-hole valence states) are observed. In a simplified picture the effect can be attributed to the combined effect of the intermediate- and final-state potential curves.