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Shear band-driven precipitate dispersion for ultrastrong ductile medium-entropy alloys

MPG-Autoren
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Körmann,  Fritz
Computational Phase Studies, Computational Materials Design, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;
Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherlands;

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Zitation

Jang, T. J., Choi, W. S., Kim, D. W., Choi, G., Jun, H., Ferrari, A., et al. (2021). Shear band-driven precipitate dispersion for ultrastrong ductile medium-entropy alloys. Nature Communications, 12(1): 4703. doi:10.1038/s41467-021-25031-6.


Zitierlink: https://hdl.handle.net/21.11116/0000-0009-43E0-E
Zusammenfassung
Precipitation strengthening has been the basis of physical metallurgy since more than 100 years owing to its excellent strengthening effects. This approach generally employs coherent and nano-sized precipitates, as incoherent precipitates energetically become coarse due to their incompatibility with matrix and provide a negligible strengthening effect or even cause brittleness. Here we propose a shear band-driven dispersion of nano-sized and semicoherent precipitates, which show significant strengthening effects. We add aluminum to a model CoNiV medium-entropy alloy with a face-centered cubic structure to form the L21 Heusler phase with an ordered body-centered cubic structure, as predicted by ab initio calculations. Micro-shear bands act as heterogeneous nucleation sites and generate finely dispersed intragranular precipitates with a semicoherent interface, which leads to a remarkable strength-ductility balance. This work suggests that the structurally dissimilar precipitates, which are generally avoided in conventional alloys, can be a useful design concept in developing high-strength ductile structural materials. © 2021, The Author(s).