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Segregation-assisted phase transformation and anti-phase boundary formation during creep of a γ′-strengthened Co-based superalloy at high temperatures

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Antonov,  Stoichko
Atom Probe Tomography, Microstructure Physics and Alloy Design, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society;
Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;

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Citation

Lu, S., Antonov, S., Xue, F., Li, L., & Feng, Q. (2021). Segregation-assisted phase transformation and anti-phase boundary formation during creep of a γ′-strengthened Co-based superalloy at high temperatures. Acta Materialia, 215: 117099. doi:10.1016/j.actamat.2021.117099.


Cite as: https://hdl.handle.net/21.11116/0000-0009-67F5-F
Abstract
In this study, the creep defects and segregation-assisted local phase transformation processes in a γ′-strengthened Co-based superalloy crept at 982 °C/248 MPa-1 and 1000 °C/137 MPa-1 were analyzed. A non-coplanar deformation configuration, i.e. a repetition of superlattice intrinsic stacking faults and antiphase boundaries (…SISF-APB…), was discovered in a Ni-free Co-based alloy, and found to be assisted by the local elemental segregation and favored more at higher stress conditions. A SISF with a/6lt;11¯2gt; type displacement in the (1¯11) plane and APB with a/2lt;110gt; type displacement nucleating in the (11¯1) plane were observed to be connected. The γ former segregation-assisted local γ′→γ phase transformation process near LPD was estimated to evolve in the order: γ′→metastable γ→γ+γ′1. The formation of metastable γ generates a new γ/γ′ interface with misfit strain/stress, which is responsible for the nucleation of dislocations, accompanied by the creep stress, thus generating APBs in the γ′ phases. The separation of γ and γ′1 seems to occur by a directional redistribution of γ and γ′ formers along the near-(1¯11) plane and toward the SISF side. The W segregation-assisted γ′→χ phase transformation along the planar fault is estimated to decrease the deformation resistance by forming SISFs with single-layer a/6lt;112gt; type displacement, while the Co segregation-assisted γ′→γ phase transformation at the LPD is believed to improve the deformation resistance by trapping the moving dislocation at the local γ/γ′ interface. © 2021