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Block-Copolymers
Mesophases
Nanostructures
Photonic Crystals
Self-Assembly
Self assembly
'current
Block co polymers
Block copolymer self-assembly
Co-polymer systems
Historical development
Photonic films
Physico-chemicals
Block copolymers
Abstract:
Block-copolymer self-assembly has proven to be an effective route for the fabrication of photonic films and, more recently, photonic pigments. However, despite extensive research on this topic over the past two decades, the palette of monomers and polymers employed to produce such structurally colored materials has remained surprisingly limited. In this Scientific Perspective, the commonly used block-copolymer systems reported in the literature are summarized (considering both linear and brush architectures) and their use is rationalized from the point of view of both their historical development and physicochemical constraints. Finally, the current challenges facing the field are discussed and promising new areas of research are highlighted to inspire the community to pursue new directions. © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.