date: 2023-06-23T15:26:27Z
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pdf:docinfo:title: E?Z Photoisomerization in Proton-Modulated Photoswitchable Merocyanine Based on Benzothiazolium and o-Hydroxynaphthalene Platform
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Keywords: E?Z photoisomerization; spiropyran; organic light-to-thermal systems; merocyanine dyes; DFT
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subject: The potential of E?Z photoisomerization in molecular organic light-to-thermal conversion and storage in an E?styryl merocyanine system was studied in a polar acidic medium. A photoswitchable styryl merocyanine dye (E)-2-(2-(2-hydroxynaphthalen-1-yl)vinyl)-3,5-dimethylbenzo[d]thiazol-3-ium iodide was synthesized for the first time. The reversible E?Z photoisomerisation of the dye was investigated using UV-Vis spectroscopy and DFT calculations. E?Z isomerization was induced through the use of visible light irradiation ( = 450 nm). The obtained experimental and theoretical results confirm the applicability of the Z and E isomers for proton-triggered light harvesting.
dc:creator: Aleksey A. Vasilev, Stanislav Baluschev, Sonia Ilieva and Diana Cheshmedzhieva
dcterms:created: 2023-06-23T15:20:57Z
Last-Modified: 2023-06-23T15:26:27Z
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title: E?Z Photoisomerization in Proton-Modulated Photoswitchable Merocyanine Based on Benzothiazolium and o-Hydroxynaphthalene Platform
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pdf:docinfo:keywords: E?Z photoisomerization; spiropyran; organic light-to-thermal systems; merocyanine dyes; DFT
pdf:docinfo:modified: 2023-06-23T15:26:27Z
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dc:title: E?Z Photoisomerization in Proton-Modulated Photoswitchable Merocyanine Based on Benzothiazolium and o-Hydroxynaphthalene Platform
modified: 2023-06-23T15:26:27Z
cp:subject: The potential of E?Z photoisomerization in molecular organic light-to-thermal conversion and storage in an E?styryl merocyanine system was studied in a polar acidic medium. A photoswitchable styryl merocyanine dye (E)-2-(2-(2-hydroxynaphthalen-1-yl)vinyl)-3,5-dimethylbenzo[d]thiazol-3-ium iodide was synthesized for the first time. The reversible E?Z photoisomerisation of the dye was investigated using UV-Vis spectroscopy and DFT calculations. E?Z isomerization was induced through the use of visible light irradiation ( = 450 nm). The obtained experimental and theoretical results confirm the applicability of the Z and E isomers for proton-triggered light harvesting.
pdf:docinfo:subject: The potential of E?Z photoisomerization in molecular organic light-to-thermal conversion and storage in an E?styryl merocyanine system was studied in a polar acidic medium. A photoswitchable styryl merocyanine dye (E)-2-(2-(2-hydroxynaphthalen-1-yl)vinyl)-3,5-dimethylbenzo[d]thiazol-3-ium iodide was synthesized for the first time. The reversible E?Z photoisomerisation of the dye was investigated using UV-Vis spectroscopy and DFT calculations. E?Z isomerization was induced through the use of visible light irradiation ( = 450 nm). The obtained experimental and theoretical results confirm the applicability of the Z and E isomers for proton-triggered light harvesting.
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pdf:docinfo:creator: Aleksey A. Vasilev, Stanislav Baluschev, Sonia Ilieva and Diana Cheshmedzhieva
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creator: Aleksey A. Vasilev, Stanislav Baluschev, Sonia Ilieva and Diana Cheshmedzhieva
meta:author: Aleksey A. Vasilev, Stanislav Baluschev, Sonia Ilieva and Diana Cheshmedzhieva
dc:subject: E?Z photoisomerization; spiropyran; organic light-to-thermal systems; merocyanine dyes; DFT
meta:creation-date: 2023-06-23T15:20:57Z
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meta:keyword: E?Z photoisomerization; spiropyran; organic light-to-thermal systems; merocyanine dyes; DFT
Author: Aleksey A. Vasilev, Stanislav Baluschev, Sonia Ilieva and Diana Cheshmedzhieva
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