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Reactive eutectic media for lignocellulosic biomass fractionation

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Schneider,  Helen
Svitlana Filonenko, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

Doskaliuk,  Nataliia
Svitlana Filonenko, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

Buchner,  Ella
Svitlana Filonenko, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus       
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Filonenko,  Svitlana       
Svitlana Filonenko, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Schneider, H., Doskaliuk, N., Buchner, E., Antonietti, M., & Filonenko, S. (2024). Reactive eutectic media for lignocellulosic biomass fractionation. ChemSusChem, 17(16): e202301780. doi:10.1002/cssc.202301780.


Cite as: https://hdl.handle.net/21.11116/0000-000F-144A-8
Abstract
This study introduces an alternative approach towards lignocellulosic biomass fractionation. For this purpose, reactive eutectic media (REM) based on ammonium formate and different organic acids are investigated, possible products are identified, and the REM are employed for lignin extraction and terminal isolation of cellulose pulp from beech wood. The method promises a considerable process intensification by simultaneous separation of high purity cellulose pulp, lignin isolation as a cationically modified species, and production of value-added chemicals from reaction products of the REM. This study puts a further focus on the generated cellulose pulp and investigates it with respect to surface charge and fiber length.