Synthesis and Properties of BaMTeS (M = Fe, Mn, Zn) and the Disordered 
Structural Analog BaGe0.5TeS

Frøen, Emil H.; Nowak, Domenic; Adler, Peter; Valldor, Martin

doi:10.1021/acs.inorgchem.4c00146

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Synthesis and Properties of BaMTeS (M = Fe, Mn, Zn) and the Disordered Structural Analog BaGe_0.5TeS

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Adler, Peter
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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引用

Frøen, E. H., Nowak, D., Adler, P., & Valldor, M. (2024). Synthesis and Properties of BaMTeS (M = Fe, Mn, Zn) and the Disordered Structural Analog BaGe_0.5TeS. Inorganic Chemistry, 63(24), 10987-10996. doi:10.1021/acs.inorgchem.4c00146.

引用: https://hdl.handle.net/21.11116/0000-000F-6B2E-7

要旨

A series of tertiary sulfide-tellurides, BaMxTeS (M = Fe, Mn, Zn, Ge), has been synthesized by solid-state synthesis. The compounds assume an orthorhombic crystal structure, described by the Cmcm (No. 63) space group, and are structural analogs of the BaMSO (M = Co, Zn) phases. The properties of all four analogs are investigated by DFT analysis. As only the BaFeTeS analog was prepared as a relatively pure phase, this homologue was subject to further experimental investigations, including heat capacity, magnetometry, and Mössbauer spectroscopy. BaFeTeS exhibits no obvious phase transition between 2 and 300 K, has no paramagnetic behavior, and lacks long-range magnetic ordering. However, the Mössbauer spectra, as well as electrical resistance data, indicate a hidden transition near 200 K that is tentatively explained by a dynamic charge-density-wave mechanism, based on a resonating valence bond (RVB) model.