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Abstract

Rapid expansion of the Li-ion pouch cell market is driven by the looming problem of permanent depletion of natural gas reservoirs and by the growing demand for high-performance portable devices and electric vehicles. Safety and performance of Li-ion cells have been two main focal points of the extensive battery research. Surfacescan
Magnetic Resonance Imaging (MRI) is an operando method designed for the accurate detection of substandard battery cells and for monitoring electrochemical processes with high spatial and temporal resolutions. Intercalation-dependent magnetism and charge transfer processes in the cell’s electrodes give rise to characteristic
magnetic field patterns outside the cell. For accurate mapping of such patterns, we proposed the concept of a unilateral radio-frequency (RF) sensor, a flat thin resonator encapsulating a proton-rich solid-state detection medium. When the pouch cell is placed in direct contact with the sensor, the magnetic field patterns propagate
inside the detection medium, and the corresponding spatial distribution of Larmor precession frequencies can be detected with MRI. In this work, we developed and evaluated a series of RF sensor configurations based on parallel-plate architecture enhanced by arrays of distributed capacitors. The parallel-plate approach does not
suffer from RF interference with pouch cells and provides excellent sensitivity and B1-field homogeneity. The optimal configuration of the parallel-plate sensor depends on the dimensions of the pouch cell and the distribution
of parallel capacitors. This article includes the results of experimental tests, RF-field simulations, and strategies to further improve the surface-scan MRI method.