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Synthesis and characterization of chlorotriarylbismuthonium salts

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Kuziola,  Jennifer
Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Nöthling,  Nils
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Leutzsch,  Markus
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Cornella,  Josep
Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kuziola, J., Nöthling, N., Leutzsch, M., & Cornella, J. (2024). Synthesis and characterization of chlorotriarylbismuthonium salts. Chemical Communications, 60(76), 10532-10535. doi:10.1039/D4CC03364G.


Cite as: https://hdl.handle.net/21.11116/0000-000F-D1EA-D
Abstract
This work reports the synthesis and structural study of a family of chlorotriarylbismuthonium salts. The abstraction of a chlorine atom with NaBArF from triarylbismuth dichloride species leads to monomeric and dimeric chlorotriarylbismuthonium species, which show a distinct behavior in solution and solid-state in comparison to their fluorotriarylbismuthonium analogues.