Incorporation of chirally deuterated putrescines into pyrrolizidine alkaloids: 
A reinvestigation

Graser, G.; Witte, L.; Robins, D. J.; Hartmann, T.

doi:10.1016/S0031-9422(98)80064-2

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Incorporation of chirally deuterated putrescines into pyrrolizidine alkaloids: A reinvestigation

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Graser, G.
Department of Biochemistry, MPI for Chemical Ecology, Max Planck Society;

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引用

Graser, G., Witte, L., Robins, D. J., & Hartmann, T. (1998). Incorporation of chirally deuterated putrescines into pyrrolizidine alkaloids: A reinvestigation. Phytochemistry, 47(6), 1017-1024. doi:10.1016/S0031-9422(98)80064-2.

引用: https://hdl.handle.net/11858/00-001M-0000-0012-A634-E

要旨

Based on previous tracer work and recent enzymatic studies it can be predicted that incorporation of (S)-1-H-2]putrescine via the symmetrical intermediate homospermidine into the necine base moiety of pyrrolizidine alkaloids (PAs) should proceed with 50