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Structurally complex molybdenum oxide model catalysts for the selective oxidation of propene

MPS-Authors
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Othman,  Nur Diana
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Abdullah,  Norli Binti
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22174

Timpe,  Olaf
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21741

Knobl,  Stefan
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21914

Niemeyer,  Dirk
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22205

Wagner,  Jakob
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22148

Su,  Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Abd Hamid, S. B., Othman, N. D., Abdullah, N. B., Timpe, O., Knobl, S., Niemeyer, D., et al. (2003). Structurally complex molybdenum oxide model catalysts for the selective oxidation of propene. Topics in Catalysis, 24(1-4), 87-95. doi:10.1023/B:TOCA.0000003080.88144.3d.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-0EF8-7
Abstract
Controlling the precipitation of molybdenum oxide in aqueous solution is a method to arrive at structurally complex solids suitable as model catalysts for selective oxidation studies. Defect geometries of the orthorhombic MoO3 (ortho-MoO3) structure that are essential for the catalytic function are fabricated as main structural motif and require no heating of the catalyst to the temperature of initial mobility of lattice oxygen. The precipitation parameters are identified and are reviewed for their relevance on the final product properties.