Nanosizing Intermetallic Compounds onto Carbon Nanotubes: Active and Selective 
Hydrogenation Catalysts

Shao, Lidong; Zhang, Wei; Armbrüster, Marc; Teschner, Detre; Girgsdies, Frank; Zhang, Bingsen; Timpe, Olaf; Friedrich, Matthias; Schlögl, Robert; Su, Dang Sheng

doi:10.1002/anie.201008013

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Nanosizing Intermetallic Compounds onto Carbon Nanotubes: Active and Selective Hydrogenation Catalysts

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Shao, Lidong
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22294

Zhang, Wei
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22163

Teschner, Detre
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21557

Girgsdies, Frank
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22288

Zhang, Bingsen
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22174

Timpe, Olaf
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22071

Schlögl, Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22148

Su, Dang Sheng
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Shao, L., Zhang, W., Armbrüster, M., Teschner, D., Girgsdies, F., Zhang, B., et al. (2011). Nanosizing Intermetallic Compounds onto Carbon Nanotubes: Active and Selective Hydrogenation Catalysts. Angewandte Chemie International Edition, 50(43), 10231-10235. doi:10.1002/anie.201008013.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-569F-D

Abstract

Active and selective Pd2Ga intermetallics supported on carbon nanotubes are synthesized and applied for alkyne hydrogenation. Intermetallics in nanoscale are necessary to achieve high mass activity, whereas ordered structures within intermetallics form high barriers for subsurface chemistry and reduce large active ensembles of Pd.