Acta Crystallographica Section E

Structure Reports Online

Volume 68, Part 7 (July 2012)


organic compounds



su2449 scheme

Acta Cryst. (2012). E68, o2118-o2119    [ doi:10.1107/S1600536812025974 ]

(E)-4-Amino-N'-(5-chloro-2-hydroxybenzylidene)benzohydrazide

H. Kargar, R. Kia and M. N. Tahir

Abstract: In the title hydrazide Schiff base compound, C14H12ClN3O2, the conformation around the C=N double bond is E. The dihedral angle between the benzene rings is 41.57 (14) Å. An intramolecular O-H...N hydrogen bond makes an S(6) ring motif. In the crystal, molecules are linked by N-H...O (bifurcated acceptor) and N-H...N hydrogen bonds, forming chains along the a axis. The interesting feature of the crystal structure is the short intermolecular C...O [3.216 (3), 3.170 (3), and 2.992 (3) Å] contacts, one of which is significantly shorter than the sum of the van der Waals radii of these atoms [3.22 Å].


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