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  Resolving the debated atomic structure of the metastable cubic SiNx tissue phase in nanocomposites with TiN

Fallqvist, A., Olovsson, W., Alling, B., Palisaitis, J., Belov, M. P., Abrikosov, I. A., et al. (2018). Resolving the debated atomic structure of the metastable cubic SiNx tissue phase in nanocomposites with TiN. Physical Review Materials, 2(9): 093608. doi:10.1103/PhysRevMaterials.2.093608.

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Datensatz-Permalink: https://hdl.handle.net/21.11116/0000-0003-A349-3 Versions-Permalink: https://hdl.handle.net/21.11116/0000-0003-A34C-0
Genre: Zeitschriftenartikel

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Fallqvist, Amie1, Autor           
Olovsson, Weine2, Autor           
Alling, Björn3, 4, Autor           
Palisaitis, Justinas5, Autor           
Belov, Maxim P.6, Autor           
Abrikosov, Igor A.7, Autor           
Hultman, Lars3, Autor           
Persson, Per Ola Åke5, Autor           
Affiliations:
1Department of Physics Chemistry and Biology, Linköping University, Linköping, SE-58183, Sweden, ou_persistent22              
2Theoretical Physics, Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden, ou_persistent22              
3Department of Physics, Chemistry and Biology (IFM), Thin Film Physics Division, Linköping University, Linköping, Sweden, ou_persistent22              
4Adaptive Structural Materials (Simulation), Computational Materials Design, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society, ou_1863339              
5Thin Film Physics Division, Department of Physics, Chemistry, and Biology (IFM), Linköping University, Linköping, Sweden, ou_persistent22              
6Materials Modeling and Development Laboratory, NUST mISIS, Moscow, Russia, ou_persistent22              
7Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-58183 Linköping, Sweden, ou_persistent22              

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 Zusammenfassung: The TiN/SiNx nanocomposite and nanolaminate systems are the archetype for super if not ultrahard materials. Yet, the nature of the SiNx tissue phase is debated. Here, we show by atomically resolved electron microscopy methods that SiNx is epitaxially stabilized in a NaCl structure on the adjacent TiN(001) surfaces. Additionally, electron energy loss spectroscopy, supported by first-principles density functional theory calculations infer that SiNx hosts Si vacancies. © 2018 American Physical Society.

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Sprache(n): eng - English
 Datum: 2018-09-20
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1103/PhysRevMaterials.2.093608
BibTex Citekey: Fallqvist2018
 Art des Abschluß: -

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Titel: Physical Review Materials
  Kurztitel : Phys. Rev. Mat.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: College Park, MD : American Physical Society
Seiten: - Band / Heft: 2 (9) Artikelnummer: 093608 Start- / Endseite: - Identifikator: ISSN: 2475-9953
CoNE: https://pure.mpg.de/cone/journals/resource/2475-9953