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  An Atom-Economical and Stereoselective Domino Synthesis of Functionalised Dienes

Souris, C., Luparia, M., Frébault, F., Audisio, D., Farès, C., Goddard, R., et al. (2013). An Atom-Economical and Stereoselective Domino Synthesis of Functionalised Dienes. Chemistry – A European Journal, 19(21), 6566-6570. doi:10.1002/chem.201300776.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-CA09-1 Version Permalink: https://hdl.handle.net/21.11116/0000-0006-E549-6
Genre: Journal Article

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chem_201300776_sm_miscellaneous_information.pdf (Supplementary material), 8MB
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https://hdl.handle.net/11858/00-001M-0000-0014-CA0B-E
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chem_201300776_sm_miscellaneous_information.pdf
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Supporting Information
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2013
Copyright Info:
Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim
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 Creators:
Souris, Caroline1, Author           
Luparia, Marco1, Author           
Frébault, Frédéric1, Author           
Audisio, Davide1, Author           
Farès, Christophe2, Author           
Goddard, Richard3, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: allylic alkylation; cyclobutene; dienes; electrocyclic reactions; palladium
 Abstract: Open sesame: A direct synthesis of functionalised and stereodefined dienes, relying on a domino allylic alkylation/electrocyclic ring-opening sequence, is reported. This method allows concise access to doubly vinylogous esters. A further systematic study of ring-opening rates of carbon-substituted cyclobutenes allowed the design of substrates amenable to sequential pericyclic reactions.

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Language(s): eng - English
 Dates: 2013-02-272013-04-092013-05-17
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.201300776
 Degree: -

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Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 19 (21) Sequence Number: - Start / End Page: 6566 - 6570 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058