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  Syntheses and structures of [(Me3N)3SiNHLi]4, (C4H8O)Al[NHSi(NMe2)3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH)4 Al]-

Bradley, J. S., Cheng, F., Archibald, S. J., Supplit, R., Rovai, R., Lehmann, C. W., et al. (2003). Syntheses and structures of [(Me3N)3SiNHLi]4, (C4H8O)Al[NHSi(NMe2)3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N)3SiNH)4 Al]-. Dalton Transactions, (9), 1846-1851. doi:10.1039/B209605F.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-9905-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-1549-0
Genre: Journal Article

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 Creators:
Bradley, John S.1, Author
Cheng, Fei1, Author
Archibald, Stephen J.1, Author
Supplit, Ralf1, Author
Rovai, Riccardo2, Author           
Lehmann, Christian W.3, Author           
Krüger, Carl4, Author           
Lefebvre, Frédéric5, Author
Affiliations:
1Department of Chemistry, University of Hull, Cottingham Road, Hull, UK, ou_persistent22              
2Research Group Bradley, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445599              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
4Service Department Krüger (XRAY), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445624              
5Laboratoire de Chimie, Organométallique de Surface, 44Bd Dull November 1918, 69616, Villeurbanne Cedex, France, ou_persistent22              

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 Abstract: The preparation of lithium tris(dimethylamino)silylamide, [(Me3N)3SiNHLi]4, 2, and its reaction with aluminium trichloride to give tris(dimethylamino)silylamino)(tetrahydrofuran)alane, (C4H8O)Al[NHSi(NMe2)3]3, 3, and bis(tetrahydrofuran)lithium tetrakis(tris(dimethylamino)silylamino)alanate, Li(THF)2+[((Me2N)3SiNH)4Al]−, 6, is reported, together with the crystal structures of 2, 3 and 6. Tris(dimethylamino)alane, ((Me2N)3SiNH)3Al, was obtained by reaction of tris(dimethylamino)silylamine with aluminium triethyl. The ammonolytic gelation of 3 to an imidoaluminosilicate gel is also described.

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Language(s): eng - English
 Dates: 2002-10-012002-12-042003-03-282003-05-01
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/B209605F
 Degree: -

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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: (9) Sequence Number: - Start / End Page: 1846 - 1851 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323