English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Diels–Alder reaction of androsta-14,16-dien-17-yl acetates with nitroethylene: Product distribution and selected adduct transformations

Baranovsky, A. V., Bolibrukh, D. A., Khripach, V. A., & Schneider, B. (2012). Diels–Alder reaction of androsta-14,16-dien-17-yl acetates with nitroethylene: Product distribution and selected adduct transformations. Steroids, 78, 282-287. doi:10.1016/j.steroids.2012.11.015.

Item is

Files

show Files
hide Files
:
NMR199.pdf (Publisher version), 357KB
 
File Permalink:
-
Name:
NMR199.pdf
Description:
-
OA-Status:
Visibility:
Restricted (Max Planck Institute for Chemical Ecology, MJCO; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Baranovsky, Alexander V., Author
Bolibrukh, Dmitry A., Author
Khripach, Vladimir A., Author
Schneider, Bernd1, Author           
Affiliations:
1Research Group Biosynthesis / NMR, MPI for Chemical Ecology, Max Planck Society, ou_421898              

Content

show
hide
Free keywords: -
 Abstract: The Diels–Alder cycloaddition of nitroethylene to some androsta-14,16-dien-17-yl acetates has been studied. The addition occurs stereoselectively, giving predominantly head-to-head-adduct. 14β-Cyanomethyl steroids were obtained via the reductive cleavage reaction of bridged nitro compounds. The structures of the new compounds have been fully characterized by 2D NMR and tandem mass-spectrometry methods.

Details

show
hide
Language(s):
 Dates: 2012-11-212012-12-19
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: Other: NMR199
DOI: 10.1016/j.steroids.2012.11.015
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Steroids
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Stoneham, MA [etc.] : Elsevier
Pages: - Volume / Issue: 78 Sequence Number: - Start / End Page: 282 - 287 Identifier: ISSN: 0039-128X
CoNE: https://pure.mpg.de/cone/journals/resource/954925446727