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  Lewis base mediated dismutation of trichlorosilane.

Singh, A. P., Ghadwal, R. S., Roesky, H. W., Holstein, J. J., Dittrich, B., Demers, J. P., et al. (2012). Lewis base mediated dismutation of trichlorosilane. Chemical Communications, (61), 7574-7576. doi:10.1039/C2CC33835A.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-000E-E509-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-C44C-D
Genre: Journal Article

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 Creators:
Singh, Amit Pratap, Author
Ghadwal, Rajendra S., Author
Roesky, Herbert W., Author
Holstein, Julian J., Author
Dittrich, Birger, Author
Demers, J. P.1, Author              
Chevelkov, V.1, Author              
Lange, A.1, Author              
Affiliations:
1Research Group of Solid-State NMR, MPI for biophysical chemistry, Max Planck Society, ou_persistent35              

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Language(s): eng - English
 Dates: 2012-06-132012
 Publication Status: Published in print
 Pages: -
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 Table of Contents: An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)2·SiCl2H2 (2), aNHC·SiCl2H2 (3), and aNHC·GeCl2 (4) have been synthesized and characterized by single crystal X-ray analysis, solid-state NMR and DFT calculations.
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C2CC33835A
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Title: Chemical Communications
Source Genre: Journal
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Pages: - Volume / Issue: (61) Sequence Number: - Start / End Page: 7574 - 7576 Identifier: ISSN: 1359-7345