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  Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds

vom Stein, T., Weigang, T., Merkens, C., Klankermayer, J., & Leitner, W. (2013). Trimethylenemethane-Ruthenium(II)-Triphos complexes as highly active catalysts for catalytic C—O bond cleavage reactions of lignin model compounds. ChemCatChem, 5(2), 439-441. doi:10.1002/cctc.201200215.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A29E-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A29F-6
Genre: Journal Article

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cctc_201200215_sm_miscellaneous_information.pdf (Supplementary material), 182KB
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https://hdl.handle.net/11858/00-001M-0000-0014-A2A0-D
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cctc_201200215_sm_miscellaneous_information.pdf
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Supporting Information
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Copyright Date:
2012
Copyright Info:
Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim
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 Creators:
vom Stein, Thorsten1, Author
Weigang, Tobias1, Author
Merkens, Carina2, Author
Klankermayer, Jürgen1, Author
Leitner, Walter1, 3, Author           
Affiliations:
1Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, 52056 Aachen, (Germany), ou_persistent22              
2Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, (Germany), ou_persistent22              
3Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445626              

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Free keywords: biomass homogeneous catalysis lignin ruthenium hydrogenation
 Abstract: Ru ready for it yet? The reaction of [Ru(cod)(methallyl)2] with tripodal phosphine ligands of the TRIPHOS-type results in the formation of Ru-trimethylenemethane complexes. Evaluation of their catalytic properties revealed a high activity for hydrogen transfer and C—O cleavage reactions including the hydrogen-free reductive cleavage of 2-aryloxy-1-arylethanols as model compounds for lignin linkages.

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Language(s): eng - English
 Dates: 2012-04-052012-08-102013-02
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/cctc.201200215
 Degree: -

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Title: ChemCatChem
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: 3 Volume / Issue: 5 (2) Sequence Number: - Start / End Page: 439 - 441 Identifier: Other: 1867-3880
CoNE: https://pure.mpg.de/cone/journals/resource/1867-3880