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  Synthetic access to a hydrocarbon-soluble trifluorinated Ge(II) compound and its Sn(II) congener.

Samuel, P. P., Li, Y., Roesky, H. W., Chevelkov, V., Lange, A., Burkhardt, A., et al. (2014). Synthetic access to a hydrocarbon-soluble trifluorinated Ge(II) compound and its Sn(II) congener. Journal of the American Chemical Society, 136(4), 1292-1295. doi:10.1021/ja412151e.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0017-C233-E Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-3B03-2
Genre: Journal Article

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http://pubs.acs.org/doi/pdf/10.1021/ja412151e (Publisher version)
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 Creators:
Samuel, P. P., Author
Li, Y., Author
Roesky, H. W., Author
Chevelkov, V.1, Author              
Lange, A.1, Author              
Burkhardt, A., Author
Dittrich, B., Author
Affiliations:
1Research Group of Solid-State NMR, MPI for Biophysical Chemistry, Max Planck Society, ou_persistent35              

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 Abstract: Trifluorinated germanium anions attracted attention of theoretical chemists already in the late 1990s to predict their physical and chemical properties. However these species were not synthesized in the laboratory, although substantial evidence for their existence was obtained from the mass. spectrometry of GeF4. The present study shows that controlled fluorination of LMNMe2 (L = PhC((NBu)-Bu-t)(2), M = Ge, Sn) using HF center dot pyridine in toluene leads to the formation of [LH2](+)[MF3](-) under elimination of HNMe2. The products contain the trifluorinated Ge(II) and Sn(II) anionic species which are stabilized by interionic H center dot center dot center dot F bonds. The new compounds were characterized by single crystal X-ray structural analysis, NMR spectroscopy, and elemental analysis.

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Language(s): eng - English
 Dates: 2014-01-072014-01-29
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/ja412151e
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Title: Journal of the American Chemical Society
Source Genre: Journal
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Pages: - Volume / Issue: 136 (4) Sequence Number: - Start / End Page: 1292 - 1295 Identifier: -