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  Long-Range Order in an Organic Overlayer Induced by Surface Reconstruction: Coronene on Ge(111)

Martínez-Blanco, J., Walter, B., Mascaraque, A., & Horn, K. (2014). Long-Range Order in an Organic Overlayer Induced by Surface Reconstruction: Coronene on Ge(111). The Journal of Physical Chemistry C, 118(22), 11699-11703. doi:10.1021/jp5015737.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-D7B0-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0024-28C1-6
Genre: Journal Article

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CnGe111_final.pdf (Any fulltext), 7MB
 
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 Creators:
Martínez-Blanco, Jesus1, Author              
Walter , Benjamin1, Author
Mascaraque, Arantzazu2, 3, Author
Horn, Karsten1, Author              
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              
2Universidad Complutense de Madrid, 28040 Madrid, Spain, ou_persistent22              
3Unidad Asociada IQFR (CSIC)−UCM, 28040 Madrid, Spain, ou_persistent22              

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 Abstract: Using scanning tunneling microscopy, we show that coronene molecules form supramolecular structures upon room-temperature deposition on Ge(111), in full commensurability with the c(2 × 8) reconstruction of the clean surface. The molecules are not adsorbed in a planar manner in the first layer; the balance between lateral intermolecular interactions and directional bonding to the surface forces them into a tilted configuration. Further coronene deposition leads to the formation of large domains of weakly bonded molecules adsorbed on top of the first layer. The ordering of the second layer is dictated by both, the first layer of molecules and the unaltered reconstructed substrate underneath. We provide a detailed analysis of the encountered molecular periodicities and discuss the mechanisms that lead to long-range ordering in these layers.

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Language(s): eng - English
 Dates: 2014-05-112014-02-132014-05-152014-05-152014-06-05
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1021/jp5015737
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Title: The Journal of Physical Chemistry C
  Other : J. Phys. Chem. C
Source Genre: Journal
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Publ. Info: Washington DC : American Chemical Society
Pages: - Volume / Issue: 118 (22) Sequence Number: - Start / End Page: 11699 - 11703 Identifier: ISSN: 1932-7447
CoNE: /journals/resource/954926947766