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Abstract:
Following our recent discovery of slow spin relaxation in the unique
[(OCuO)-O-III](-) anion located in the apatite-type pigment
A(10)(PO4)(6)-(CuxOH1-x-y)(2), where A = Sr, we present the magnetic
behavior of this anion for the cases of A = Ca and Ba, which provides
evidence for a cation field impact on the properties of a single-ion
magnet molecular anion.