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  Stainless Steel Mesh-supported NiS nanosheet Array as Highly Efficient Catalyst for Oxygen Evolution Reaction

Chen, J. S., Ren, J., Shalom, M., Fellinger, T., & Antonietti, M. (2016). Stainless Steel Mesh-supported NiS nanosheet Array as Highly Efficient Catalyst for Oxygen Evolution Reaction. ACS Applied Materials and Interfaces, 8(8), 5509-5516. doi:10.1021/acsami.5b10099.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-AA46-5 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-EFBC-2
Genre: Journal Article
Alternative Title : ACS Applied Materials & Interfaces

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 Creators:
Chen, Jun Song1, Author              
Ren, Jiawen2, Author              
Shalom, Menny3, Author              
Fellinger, Tim1, Author              
Antonietti, Markus2, Author              
Affiliations:
1Tim Fellinger, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863322              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              
3Menny Shalom, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2205635              

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 Abstract: Nickel (II) sulfide (NiS) nanosheets with a thickness of 10 nm and a size of 200 nm were facilely grown on stainless steel (SLS) meshes via a one-pot hydrothermal method. This unique construction renders an excellent electrical contact between the porous film of active NiS sheets and the highly conductive substrate, which exhibits a superior catalytic activity towards oxygen evolution reaction (OER). The NiS@SLS electrocatalyst exhibits an unusually low overpotential of 297 mV (i.e., 1.524 V vs. RHE) at a current density of 11 mA?cm-2, and an extra small Tafel slope of only 47 mV?dec-1 proves an even more competitive performance at high to very high current densities. This performance compares very favorably to other Ni-based catalysts and even to the precious state-of-the-art IrO2 or RuO2 catalyst.

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 Dates: 2016-02-052016
 Publication Status: Published in print
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 Identifiers: DOI: 10.1021/acsami.5b10099
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Title: ACS Applied Materials and Interfaces
  Abbreviation : ACS Appl. Mater. Interfaces
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 8 (8) Sequence Number: - Start / End Page: 5509 - 5516 Identifier: ISSN: 1944-8244