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  Chiral Analysis Using Broadband Rotational Spectroscopy

Shubert, V. A., Schmitz, D., Pérez, C., Medcraft, C., Krin, A., Domingos, S. R., et al. (2016). Chiral Analysis Using Broadband Rotational Spectroscopy. The Journal of Physical Chemistry Letters, 7(2), 341-350. doi:10.1021/acs.jpclett.5b02443.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-AA7C-F Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-AA7D-D
Genre: Journal Article

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http://dx.doi.org/10.1021/acs.jpclett.5b02443 (Publisher version)
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 Creators:
Shubert, V. Alvin1, 2, Author              
Schmitz, David1, 2, Author              
Pérez, Cristóbal1, 2, 3, Author              
Medcraft, Chris1, 2, Author              
Krin, Anna1, 2, Author              
Domingos, Sérgio R.1, 2, 3, Author              
Patterson, David4, Author
Schnell, Melanie1, 2, 3, Author              
Affiliations:
1Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
2Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany, ou_persistent22              
3The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany, ou_persistent22              
4Department of Physics, Harvard University, Cambridge, Massachusetts 02138, United States, ou_persistent22              

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 Abstract: Broadband microwave spectroscopy is a proven tool to precisely determine molecular properties of gas-phase molecules. Recent developments make it applicable to investigate chiral molecules. Enantiomers can be differentiated, and the enantiomeric excess and, indirectly, the absolute configuration can be determined in a molecule-selective manner. The resonant character and high resolution of rotational spectroscopy provide a unique mixture compatibility. Future directions, such as extending the technique to chemical analysis, are discussed.

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Language(s): eng - English
 Dates: 2015-11-022015-12-292015-12-292016-01-21
 Publication Status: Published in print
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1021/acs.jpclett.5b02443
 Degree: -

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Title: The Journal of Physical Chemistry Letters
  Abbreviation : J. Phys. Chem. Lett.
Source Genre: Journal
 Creator(s):
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 7 (2) Sequence Number: - Start / End Page: 341 - 350 Identifier: CoNE: /journals/resource/1948-7185