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  Chiral Analysis Using Broadband Rotational Spectroscopy

Shubert, V. A., Schmitz, D., Pérez, C., Medcraft, C., Krin, A., Domingos, S. R., et al. (2016). Chiral Analysis Using Broadband Rotational Spectroscopy. The Journal of Physical Chemistry Letters, 7(2), 341-350. doi:10.1021/acs.jpclett.5b02443.

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http://dx.doi.org/10.1021/acs.jpclett.5b02443 (Publisher version)
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 Creators:
Shubert, V. Alvin1, 2, Author           
Schmitz, David1, 2, Author           
Pérez, Cristóbal1, 2, 3, Author           
Medcraft, Chris1, 2, Author           
Krin, Anna1, 2, Author           
Domingos, Sérgio R.1, 2, 3, Author           
Patterson, David4, Author
Schnell, Melanie1, 2, 3, Author           
Affiliations:
1Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
2Center for Free-Electron Laser Science, Luruper Chaussee 149, D-22761 Hamburg, Germany, ou_persistent22              
3The Hamburg Centre for Ultrafast Imaging, Universität Hamburg, Luruper Chaussee 149, D-22761 Hamburg, Germany, ou_persistent22              
4Department of Physics, Harvard University, Cambridge, Massachusetts 02138, United States, ou_persistent22              

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 Abstract: Broadband microwave spectroscopy is a proven tool to precisely determine molecular properties of gas-phase molecules. Recent developments make it applicable to investigate chiral molecules. Enantiomers can be differentiated, and the enantiomeric excess and, indirectly, the absolute configuration can be determined in a molecule-selective manner. The resonant character and high resolution of rotational spectroscopy provide a unique mixture compatibility. Future directions, such as extending the technique to chemical analysis, are discussed.

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Language(s): eng - English
 Dates: 2015-11-022015-12-292015-12-292016-01-21
 Publication Status: Issued
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.jpclett.5b02443
 Degree: -

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Title: The Journal of Physical Chemistry Letters
  Abbreviation : J. Phys. Chem. Lett.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 7 (2) Sequence Number: - Start / End Page: 341 - 350 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/1948-7185