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  Interaction of SO2 with copper and copper oxide surfaces

Baxter, J., Grunze, M., & Kong, C. (1988). Interaction of SO2 with copper and copper oxide surfaces. Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films, 6(3), 1123-1127. doi:10.1116/1.575657.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-8C82-E Version Permalink: https://hdl.handle.net/21.11116/0000-0001-8C83-D
Genre: Journal Article

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JVacuumSciTechnolA_6_1988_1123.pdf (Any fulltext), 555KB
 
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 Creators:
Baxter, J., Author
Grunze, M.1, Author           
Kong, C.W., Author
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: The adsorption and reaction of SO2 with copper and copper oxide surfaces was studied by in situ x‐ray photoelectron spectroscopy between 173 and 473 K and pressures ranging from UHV to 10−1 mbar. It was found that a Cu2SO3 species acts as an intermediate in the formation of CuSO4 at T<300 K, and at T>300 K in the formation of copper sulfide. The presence of gas‐phase oxygen was found to accelerate the surface reaction between SO2 and the substrates. In this communication we will focus on the experiments on Cu2O surfaces and discuss our results in the context of the SO2–flue‐gas cleanup process on copper oxide.

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Language(s): eng - English
 Dates: 1987-10-011987-12-071998-06-041988
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1116/1.575657
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Title: Journal of Vacuum Science and Technology A: Vacuum, Surfaces, and Films
  Other : J. Vac. Sci. Technol. A: Vac. Surf. Films
Source Genre: Journal
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Publ. Info: New York : Published by AVS through the American Institute of Physics
Pages: - Volume / Issue: 6 (3) Sequence Number: - Start / End Page: 1123 - 1127 Identifier: ISSN: 0734-2101
CoNE: https://pure.mpg.de/cone/journals/resource/954928495416_2