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  A Purely Organic Tricarbanion

Höfler, D., Goddard, R., Lingnau, J. B., Nöthling, N., & List, B. (2018). A Purely Organic Tricarbanion. Angewandte Chemie International Edition, 57(27), 8326-8329. doi:10.1002/anie.201803647.

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Hoefler, Goddard, Lingnau, Noethling, List 2018.pdf (Postprint), 592KB
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Hoefler, Goddard, Lingnau, Noethling, List 2018.pdf
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 Creators:
Höfler, Denis1, Author           
Goddard, Richard2, Author           
Lingnau, Julia B.3, Author           
Nöthling, Nils2, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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Free keywords: carbanions; highly charged anions; purely organic tricarbanion; tetraalkylammonium cation; triflyl stabilization
 Abstract: How many carbanions can an organic molecule accommodate? The formation of purely organic carbanions with multiple charges is challenging as charge stabilization cannot be achieved through metal coordination. Previously, only quaternary ammonium dicarbanion salts had been reported. By using highly electron-deficient trifluoromethane-sulfonyl (triflyl or Tf) groups,the formation of apurely organic tricarbanion has been realized for the first time.

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Language(s): eng - English
 Dates: 2018-03-262018-04-242018-04-242018-07-02
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201803647
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 57 (27) Sequence Number: - Start / End Page: 8326 - 8329 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851