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  Hydrogenative Cyclopropanation and Hydrogenative Metathesis

Peil, S., Guthertz, A., Biberger, T., & Fürstner, A. (2019). Hydrogenative Cyclopropanation and Hydrogenative Metathesis. Angewandte Chemie International Edition, 58(26), 8851-8856. doi:10.1002/anie.201904256.

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ange201904256-sup-0001-misc_information.pdf (Supplementary material), 11MB
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 Creators:
Peil, Sebastian1, Author              
Guthertz, Alexandre1, Author              
Biberger, Tobias1, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: carben complexes; cyclopropanation; enynes; hydrogenation; metathesis; ruthenium
 Abstract: The unusual geminal hydrogenation of a propargyl alcohol derivative with [CpXRuCl] as the catalyst entails formation of pianostool ruthenium carbenes in the first place; these reactive intermediates can be intercepted with tethered alkenes to give either cyclopropanes or cyclic olefins as the result of a formal metathesis event. The course of the reaction is critically dependent on the substitution pattern of the alkene trap.

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Language(s): eng - English
 Dates: 2019-04-072019-04-262019-06-24
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201904256
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie, International Edition
  Other : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 58 (26) Sequence Number: - Start / End Page: 8851 - 8856 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851