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  Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

Sharma, M. K., Rottschäfer, D., Blomeyer, S., Neumann, B., Stammler, H.-G., van Gastel, M., et al. (2019). Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework. Chemical Communications, 55(70), 10408-10411. doi:10.1039/C9CC04701H.

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 Creators:
Sharma, Mahendra K.1, Author
Rottschäfer, Dennis1, Author
Blomeyer, Sebastian1, Author
Neumann, Beate1, Author
Stammler, Hans-Georg1, Author
van Gastel, Maurice2, Author              
Hinz, Alexander3, Author
Ghadwal, Rajendra S.1, Author
Affiliations:
1Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstr. 25, Bielefeld, Germany , ou_persistent22              
2Research Group van Gastel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541713              
3Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany , ou_persistent22              

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 Abstract: The synthesis and characterization of the crystalline diphosphene radical cations [{(NHC)C(Ph)}P]2(GaCl4) (NHC = IPr = C{(NDipp)CH}2 3, SIPr = C{(NDipp)CH2}2 4; Dipp = 2,6-iPr2C6H3) and dications [{(NHC)C(Ph)}P]2(GaCl4)2 (NHC = IPr 5, SIPr 6) featuring a π-conjugated C2P2C2-framework has been reported.

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Language(s): eng - English
 Dates: 2019-06-192019-08-052019-08-052019-09-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C9CC04701H
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 55 (70) Sequence Number: - Start / End Page: 10408 - 10411 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413