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  Biomimetic synthesis of sub-20 nm covalent organic frameworks in water

Franco, C., Rodríguez-San-Miguel, D., Sorrenti, A., Sevim, S., Pons, R., Platero-Prats, A. E., et al. (2020). Biomimetic synthesis of sub-20 nm covalent organic frameworks in water. Journal of the American Chemical Society, 142(7), 3540-3547. doi:10.1021/jacs.9b12389.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-BFF9-C Version Permalink: http://hdl.handle.net/21.11116/0000-0005-BFFA-B
Genre: Journal Article

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 Creators:
Franco, Carlos, Author
Rodríguez-San-Miguel, David, Author
Sorrenti, Alessandro, Author
Sevim, Semih, Author
Pons, Ramon, Author
Platero-Prats, Ana E., Author
Pavlović, Marko1, Author              
Szilágyi, Istvan, Author
Gonzalez, Ruiz, Author
Luisa, M., Author
González-Calbet, José M., Author
Bochicchio, Davide, Author
Pesce, Luca, Author
Pavan, Giovanni M., Author
Imaz, Inhar, Author
Cano-Sarabia, Mary, Author
Maspoch, Daniel, Author
Pané, Salvador, Author
de Mello, Author
J., Andrew, Author
Zamora, Felix, AuthorPuigmartí-Luis, Josep, Author more..
Affiliations:
1Lukas Zeininger, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3179204              

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 Abstract: Covalent organic frameworks (COFs) are commonly synthesized under harsh conditions yielding unprocessable powders. Control in their crystallization process and growth has been limited to studies conducted in hazardous organic solvents. Herein, we report a one-pot synthetic method that yields stable aqueous colloidal solutions of sub-20 nm crystalline imine-based COF particles at room temperature and ambient pressure. Additionally, through the combination of experimental and computational studies, we investigated the mechanisms and forces underlying the formation of such imine-based COF colloids in water. Further, we show that our method can be used to process the colloidal solution into 2D and 3D COF shapes as well as to generate a COF ink that can be directly printed onto surfaces. These findings should open new vistas in COF chemistry, enabling new application areas.

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Language(s): eng - English
 Dates: 2020-01-272020
 Publication Status: Published in print
 Pages: -
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 Identifiers: DOI: 10.1021/jacs.9b12389
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Title: Journal of the American Chemical Society
  Other : J. Am. Chem. Soc.
  Abbreviation : JACS
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 142 (7) Sequence Number: - Start / End Page: 3540 - 3547 Identifier: ISSN: 0002-7863