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  Zintl Defects in Intermetallic Clathrates

Baitinger, M., Böhme, B., Wagner, F. R., & Schwarz, U. (2020). Zintl Defects in Intermetallic Clathrates. Zeitschrift für anorganische und allgemeine Chemie, 646, 1-9. doi:10.1002/zaac.202000107.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0006-980C-2 Version Permalink: http://hdl.handle.net/21.11116/0000-0006-AA8C-D
Genre: Journal Article

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 Creators:
Baitinger, Michael1, Author              
Böhme, Bodo2, Author              
Wagner, Frank R.3, Author              
Schwarz, Ulrich4, Author              
Affiliations:
1Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863416              
2Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863408              
3Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863409              
4Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              

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 Abstract: Dedicated to Prof. Yuri Grin on the Occasion of his 65th Birthday In many cases, idealized crystal structure models cannot rationalize the actual properties of intermetallic compounds. For a realistic approach in materials research, microstructures and defects need to be taken into account. In case of clathrate compounds, particularly the intrinsic framework vacancies (denoted as Zintl defects) demand consideration. Consequently, clathrate research produces evidence that modern-day structure chemistry involves the utilization of advanced X-ray diffraction methods combined with elaborated bulk phase analyses, the investigation of phase relations, and the study of mutual interrelations in the triangle chemical bonding–structure–properties. Herein, we review some fundamental contributions to the specific defect chemistry of intermetallic clathrates. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH Co. KGaA.

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Language(s): eng - English
 Dates: 2020-06-092020-06-09
 Publication Status: Published in print
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 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1002/zaac.202000107
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : J. Inorg. Gen Chem.
  Other : Journal of Inorganic and General Chemistry
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 646 Sequence Number: - Start / End Page: 1 - 9 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895