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  Dynamical properties of chemical systems near Hopf bifurcation points

Ipsen, M., & Schreiber, I. (2000). Dynamical properties of chemical systems near Hopf bifurcation points. Chaos, 10(4), 791-802. doi:10.1063/1.1311980.

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1.1311980.pdf (Publisher version), 664KB
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 Creators:
Ipsen, Mads1, Author           
Schreiber, I.2, Author
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              
2Department of Chemical Engineering, Prague Institute of Chemical Technology, Technická 5, 166 28 Prague 6, Czech Republic, ou_persistent22              

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 Abstract: In this paper, we numerically investigate local properties of dynamical systems close to a Hopf bifurcation instability. We focus on chemical systems and present an approach based on the theory of normal forms for determining numerical estimates of the limit cycle that branches off at the Hopf bifurcation point. For several numerically ill-conditioned examples taken from chemical kinetics, we compare our results with those obtained by using traditional approaches where an approximation of the limit cycle is restricted to the center subspace spanned by critical eigenvectors, and show that inclusion of higher-order terms in the normal form expansion of the limit cycle provides a significant improvement of the limit cycle estimates. This result also provides an accurate initial estimate for subsequent numerical continuation of the limit cycle.

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Language(s): eng - English
 Dates: 1999-12-302000-07-192000-12
 Publication Status: Issued
 Pages: 12
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.1311980
 Degree: -

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Title: Chaos
  Other : Chaos : an interdisciplinary journal of nonlinear science
Source Genre: Journal
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Publ. Info: Woodbury, NY : American Institute of Physics
Pages: 12 Volume / Issue: 10 (4) Sequence Number: - Start / End Page: 791 - 802 Identifier: ISSN: 1054-1500
CoNE: https://pure.mpg.de/cone/journals/resource/954922836228