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Abstract:
The Pt(110) surface facets during the catalytic oxidation of CO, if reaction conditions are adjusted such that the CO‐induced 1×1⇄1×2 phase transition can take place simultaneously. A detailed low‐energy electron diffraction beam profile analysis revealed that regularly spaced (430) and (340) facets are formed with a lateral periodicity of ∼70 lattice units along the [11̄0] direction. This result, together with the observation that the facetted surface is only stable under reaction conditions, indicates a dissipative structure of the Turing type. Such structures, which are stationary but exhibit a periodic variation of the concentration variables in space, have so far almost exclusively been discussed theoretically. The interpretation of the facetted surface as a Turing structure could be confirmed by a Monte Carlo simulation based on the Langmuir Hinshelwood mechanism of catalytic CO oxidation and the CO‐induced 1×1⇄1×2 phase transition.