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  A simple kinetic model of preferential solvation in binary mixtures

Petrov, N. K., Wiessner, A., & Staerk, H. (2001). A simple kinetic model of preferential solvation in binary mixtures. Chemical Physics Letters, 349(5-6), 517-520. Retrieved from http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TFN-44D4R1P-9-1H&_cdi=5231&_user=38661&_pii=S0009261401012519&_origin=search&_coverDate=12%2F07%2F2001&_sk=996509994&view=c&wchp=dGLbVlW-zSkzV&md5=82038f4bcab429d095eccccd0c281443&ie=/sdarticle.pdf.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0012-F504-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0029-BDAB-C
Genre: Journal Article

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 Creators:
Petrov, N. K.1, Author              
Wiessner, A.2, Author              
Staerk, H.2, Author              
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for biophysical chemistry, Max Planck Society, ou_578564              
2Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society, ou_578624              

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 Abstract: Based on experimental data a kinetic model is presented that adequately describes the main features of preferential solvation of a charge-transfer dipole in binary mixtures. 8- (N,N-dimethylamino)-11H-indeno[2,1-a]pyrene is used as fluorescent probe in toluene/DMSO mixtures. The observed saturation behavior can be understood in terms of microclusters of polar molecules surrounding the solute dipolar species. In such an approach, the size of the microclusters is mainly determined by interfacial surface tension. (C) 2001 Published by Elsevier Science B.V.

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Language(s): eng - English
 Dates: 2001-12-07
 Publication Status: Published in print
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 Rev. Method: Peer
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Title: Chemical Physics Letters
Source Genre: Journal
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Pages: - Volume / Issue: 349 (5-6) Sequence Number: - Start / End Page: 517 - 520 Identifier: -