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  Molybdenum Difluoride Dioxide, MoO2F2

Shorafa, H., Ficicioglu, H., Tamadon, F., Girgsdies, F., & Seppelt, K. (2010). Molybdenum Difluoride Dioxide, MoO2F2. Inorganic Chemistry, 49(9), 4263-4267. doi:10.1021/ic1000864.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0011-2AC5-A Version Permalink: https://hdl.handle.net/21.11116/0000-0005-F48B-B
Genre: Journal Article

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787546.pdf (Any fulltext), 810KB
 
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 Creators:
Shorafa, Hashem1, Author
Ficicioglu, Halil1, Author
Tamadon, Farhad1, Author
Girgsdies, Frank2, Author           
Seppelt, Konrad1, Author
Affiliations:
1Anorganische und Analytische Chemie, Institut für Chemie, Freie Universität, Fabeckstrasse 34-36, D-14195 Berlin, Germany, ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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Free keywords: MoO2F2
 Abstract: MoO2F2 is prepared by pyrolysis of (Na+H2O)2 cis−MoO2F42−. A preliminary model of the structure is obtained from powder data: it has a triangular columnar structure with three fluorine bridges between the three molybdenum atoms and with oxygen bridges between the layers. (a = 1605, b = 384, c = 1395 pm, Pnma, Z = 12). The closest related structure is that of TiF4, except that the orientation of the triangular columns is different.

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Language(s): eng - English
 Dates: 2010-04-092010-05-03
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ic1000864
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Title: Inorganic Chemistry
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 49 (9) Sequence Number: - Start / End Page: 4263 - 4267 Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669