Molybdenum Difluoride Dioxide, MoO2F2

Shorafa, Hashem; Ficicioglu, Halil; Tamadon, Farhad; Girgsdies, Frank; Seppelt, Konrad

doi:10.1021/ic1000864

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Molybdenum Difluoride Dioxide, MoO₂F₂

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Girgsdies, Frank
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Shorafa, H., Ficicioglu, H., Tamadon, F., Girgsdies, F., & Seppelt, K. (2010). Molybdenum Difluoride Dioxide, MoO₂F₂. Inorganic Chemistry, 49(9), 4263-4267. doi:10.1021/ic1000864.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-2AC5-A

Abstract

MoO2F2 is prepared by pyrolysis of (Na+H2O)2 cis−MoO2F42−. A preliminary model of the structure is obtained from powder data: it has a triangular columnar structure with three fluorine bridges between the three molybdenum atoms and with oxygen bridges between the layers. (a = 1605, b = 384, c = 1395 pm, Pnma, Z = 12). The closest related structure is that of TiF4, except that the orientation of the triangular columns is different.