Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by 
Formal Catalytic Hydrocarboxylation

Ostapowicz, Thomas G.; Schmitz, Marc; Krystof, Monika; Klankermayer, Jürgen; Leitner, Walter

doi:10.1002/anie.201304529

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Carbon Dioxide as a C₁ Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

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Leitner, Walter
Institut für Technische und Makromolekulare Chemie RWTH Aachen University;
Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W. (2013). Carbon Dioxide as a C₁ Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation. Angewandte Chemie International Edition, 52(46), 12119-12123. doi:10.1002/anie.201304529.

引用: https://hdl.handle.net/11858/00-001M-0000-0014-C9E3-E

要旨

A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO₂, and H₂. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water–gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst.