Ba3[FeN3]: Ein neues Nitridoferrat(III) mit [CO3]2−-isosteren Anionen [FeN3]6−

Höhn, P.; Kniep, R.; Rabenau, A.

doi:10.1524/zkri.1991.196.1-4.153

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Ba₃[FeN₃]: Ein neues Nitridoferrat(III) mit [CO₃]²⁻-isosteren Anionen [FeN₃]⁶⁻

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Citation

Höhn, P., Kniep, R., & Rabenau, A. (1991). Ba₃[FeN₃]: Ein neues Nitridoferrat(III) mit [CO₃]²⁻-isosteren Anionen [FeN₃]⁶⁻. Zeitschrift für Kristallographie, 196(1-4), 153-158. doi:10.1524/zkri.1991.196.1-4.153.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-B7DE-0

Abstract

Ba3[FeN3] [hexagonal, P6(3)/m (Nr. 176); a = 801.4(1) pm, c = 560.8(1) pm; Z = 2] was prepared by reaction of barium with nitrogen in iron-crucibles at 1000-degrees-C. The crystal structure contains trigonal-planar anions [FeN3]6- which are isosteric to carbonate-ions [Fe-N: 173.0(12) pm]. The homologous compound Sr3[FeN3] was determined to be an isotype of Ba3[FeN3].