Palladium(III)-catalyzed fluorination of arylboronic acid derivatives

Mazzotti, Anthony R.; Campbell, Michael G.; Tang, Pingping; Murphy, Jennifer M.; Ritter, Tobias

doi:10.1021/ja405919z

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Palladium(III)-catalyzed fluorination of arylboronic acid derivatives

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Mazzotti, A. R., Campbell, M. G., Tang, P., Murphy, J. M., & Ritter, T. (2013). Palladium(III)-catalyzed fluorination of arylboronic acid derivatives. Journal of the American Chemical Society, 135(38), 14012-14015. doi: 10.1021/ja405919z.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-3BF9-C

Abstract

A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.